Be Extra Cautious with Acid-Based Furnaces for Aluminum Deoxidation
Brittle fracture is one of the common defects in investment castings. Especially when using induction furnaces (medium frequency induction furnace, low frequency induction furnace) with acidic furnace linings for melting and using aluminum for deoxidation, the cast steel parts are more prone to brittle fracture during pouring.
Ⅰ.Overview
The investment casting with brittle fracture is shown in Figure 1. The macroscopic fracture grains of brittle fracture castings are coarse and resemble rock sugar, as shown in Figure 2. The microstructure of brittle fracture castings is shown in Figure 3.

Figure1. Brittle fracture of investment casting

FIG. 2 Macroscopic fracture of brittle fracture

Aluminides on grain boundaries 100X Carbon-boron compounds at grain boundaries 160X
FIG. 3 Microstructure of brittle fracture
Ⅱ. The cause
(1) The amount of residual aluminum in the casting is too high, the smelting process is improper or improper operation, so that the residual aluminum in the casting is too high, and aluminum compounds are formed on the grain boundary, such as aluminum nitride, which causes the brittle fracture of the casting.
(2) The residual amount of boron in the casting is high. On the grain boundary of the casting, the carbon-boron compound [M23(C•B)6] precipitates along the austenite grain boundary. Carbon and boron compounds cause brittle fracture of castings. ① The boric acid in the furnace lining material is decomposed at high temperature and enters the metal liquid during smelting. ② High boron content in the charge.
(3) Cleaning the casting method or improper use of the casting under the superposition of residual stress and external force, exceeding the strength limit of the casting at this time, brittle fracture occurs.
Ⅲ. Preventive measure
(1) Strictly control the amount of residual aluminum in castings. The Si-Ca and Al combined deoxidation method is used instead of a single aluminum deoxidation. (2) Control the amount of aluminum added, including the sedation of aluminum and final deoxidation of aluminum controlled in the liquid metal 0.8% ~ 1.2% (the amount of aluminum added and the condition of the charge is very important, when the charge rust is serious, the amount added is the upper limit, and the lower limit is taken); The residual aluminum content of castings is 0.03% ~ 0.07%.
(2) Control the boron content in the liquid metal so that the boron content in the casting is less than 0.005%. ① Improve the furnace building process, and strictly control the amount of boric acid added when filling the furnace. ② Strictly control the boron content in the charge.
(3) Improve the way of cleaning castings or using castings to avoid sudden impact of external force.